In a large bowl, whisk together the melted butter, egg yolk, buttermilk, and vanilla.
Next, sprinkle the flour, baking powder, baking soda, salt, brown sugar, cinnamon, and cloves on top of the butter mixture.
Stir very well to combine everything. The batter will seem slightly dry, and that's fine--make sure all the flour is incorporated.
Stir in the chopped pears.
Divide the batter between the muffin cups.